Note

KEYES, TE;WELDON, F;MULLER, E;PECHY, P;GRATZEL, M;VOS, JG

1995

August

APPLICATION OF DEUTERIATION TO DETERMINE THE LOCATION OF THE EMITTING STATE IN MIXED-LIGAND RU-II POLYPYRIDYL COMPLEXES

Published

1

24 ()

TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) ION PHOTOCHEMICAL PROPERTIES AQUEOUS-SOLUTION EXCITED-STATE TRIS(BIPYRIDINE)RUTHENIUM(II) RUTHENIUM(II) SPECTRA

The location of the emitting triplet state in heteroleptic Ru-II polypyridyl complexes has been determined by a new method using deuteriated ligands and emission-lifetime measurements, and a new single-step, high yield synthesis of perdeuteriated 2.2'-bipyridyl has been developed.

CAMBRIDGE

ROYAL SOC CHEMISTRY

0300-9246

2705

2706